Do tints or shades of colors in the color wheel determine different complementary colors?

By tints or shades of color wheel colors, I mean:





Red:


Scarlet


Crimson





Blue:


Navy


Ultramarine





Yellow:


Golden Yellow


Canary Yellow





Green:


Olive


Grass





Purple:


Orchid


Lavender





Orange:


Sienna


Vermilion(Red mixed with orange)





Not sure about Indigo, though...





Do I need specific tints and shades of complementary colors to go with those? Or does it not matter?





Because I don%26#039;t exactly have a full set of Prismacolor pencils but I do have some. and want to use them in the future.
Do tints or shades of colors in the color wheel determine different complementary colors?
Vermillion...complement is Blue-green opposite of red and yellow...which is Vermillion.


Just work it out... what color would be across the wheel.





EDIT: Hue is color, tint is hue with white added, shade is hue with complement added (or if really crass..black)